New Newbie - getting started on switchover from Coldfusion

I'm an experienced web developer switching from CF to .NET, and just learning OOP and C# in VS 2008.

Of the serveal million questions I have, the 1st have to do with getting accustomed to the VS environment and really understanding the files & folder heirarchy involved in a project.

Then I could use some verrrry simple examples of connecting to a sql database, binding the dataobjects to controls, and then manipulating data.  I've downloaded the employee-info-web-starter-kit, but that's still a bit complex at this juncture (though it did lead to my asking these questions). 

Can anyone recommend a resource or book tailored to my needs?  I'd be most grateful!

Thanks,
Richard