How Create a new Column in a Datable and assign value to the newly created column row

SqlDataAdapter adp2 = new SqlDataAdapter("select source, destination, vehicle, rate from pickupdroptariff order by source", conn);
        DataTable dt2 = new DataTable();
        adp2.Fill(dt2);
        dt2.Columns.Add("Rate_New");
        int veh_rate=0;
        if (dt2.Rows.Count > 0)
        {
            for (int j = 0; j < dt2.Rows.Count; j++)
            {
                if(dt2.Rows[j][2].ToString()=="Small Car")
                {
                    veh_rate = Convert.ToInt32(dt2.Rows[j][3].ToString());
                    veh_rate = veh_rate + small;
                    //DataRow row = null;
                    //row[4] = veh_rate.ToString();
                    //dt2.Rows.Add(row);
 
                    dt2.Rows.Add("small",veh_rate.ToString());
                }
                if(dt2.Rows[j][2].ToString()=="Regular Car")
                {
                    veh_rate = Convert.ToInt32(dt2.Rows[j][3].ToString());
                    veh_rate = veh_rate + regular;
                    dt2.Rows.Add("Regular", veh_rate.ToString());
                }
                if(dt2.Rows[j][2].ToString()=="Luxury Car")
                {
                    veh_rate = Convert.ToInt32(dt2.Rows[j][3].ToString());
                    veh_rate = veh_rate + luxury;
                    dt2.Rows.Add("Luxury", veh_rate.ToString());
                }
            }
        }
        GridView1.DataSource = dt2;
        GridView1.DataBind();