Steps Involved:
- Open SharePoint 2010 Management Shell by going to Start | All Programs | SharePoint | Microsoft SharePoint 2010 Products | SharePoint 2010 Management Shell (Run as Administrator).
- Run the following script.
Powershell Script: ## Input Parameters required for attaching a file to the list item $uri="http://serverName:10736/sites/ECT/_vti_bin/Lists.asmx?wsdl" [string] $listItemId="3" [string] $listName="List" [string] $fPath = "D:\Lists.xml" ## Check if the file exists in the path specified if([System.IO.File]::Exists($fPath)) { ## Read the file $fStream=[System.IO.File]::OpenRead($fPath) [String] $fName=$fStream.Name [System.Byte[]]$bytes=New-Object -TypeName System.Byte[] -ArgumentList $fStream.Length $fStream.Read($bytes, 0, [int]$fStream.Length) $fStream.Close() ## Attach the file to the list item using web service $listWebServiceReference = New-WebServiceProxy -Uri $uri -UseDefaultCredential Write-Host -ForegroundColor Magenta "Adding the attachement to the list item........." $listWebServiceReference.AddAttachment($listName,$listItemId,$fName,$bytes) Write-Host -ForegroundColor Green $fName " is attached successfully to the list item" } else { Write-Host -ForegroundColor Yellow "File does not exists in the specified path " $fPath }
For more information on New-WebServiceProxy please refer http://technet.microsoft.com/en-us/library/dd315258.aspx.

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